Equilibrium studies of extraction of levulinic acid by (trioctylamine (TOA) plus ester) solvents

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dc.contributor.authorUslu, Hasan
dc.contributor.authorKirbaslar, S. Ismail
dc.date.accessioned2024-03-13T10:35:19Z
dc.date.available2024-03-13T10:35:19Z
dc.date.issued2008
dc.departmentİstanbul Beykent Üniversitesien_US
dc.description.abstractReactive extraction of levulinic acid has been done at 298.15 K. All experiments are reported on the extraction of levulinic acid by trioctylamine JOA) dissolved in I I different ester solvents (ethyl propionate, dimethyl phthalate, hexyl acetate, cyclohexyl acetate, dimethyl adipate, propyl acetate,, dimethyl glutarate, dimethyl fumarate, diethyl sebacate, and diethyl carbonate), as well as single solvents. Experimental results of batch extraction experiments are calculated and reported as distribution coefficients (K-D= (c) over bar (HA)/C-HA,C-total), loading factors (TT), stoichiometric loading factor (T-s), separation factor (S-f), and extraction efficiency (E). The diethyl carbonate was found to be the most effective solvent with a maximum distribution value of 5.75. Maximum values of possible equilibrium complexation constants for (acid + amine) (1:1) K, and (2:1) K-21 were determined as 3.32 and 32.59 for diethyl carbonate, respectively.en_US
dc.identifier.doi10.1021/je800099a
dc.identifier.endpage1563en_US
dc.identifier.issn0021-9568
dc.identifier.issue7en_US
dc.identifier.scopus2-s2.0-51949094924en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage1557en_US
dc.identifier.urihttps://doi.org/10.1021/je800099a
dc.identifier.urihttps://hdl.handle.net/20.500.12662/4340
dc.identifier.volume53en_US
dc.identifier.wosWOS:000257543300025en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherAmer Chemical Socen_US
dc.relation.ispartofJournal Of Chemical And Engineering Dataen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.titleEquilibrium studies of extraction of levulinic acid by (trioctylamine (TOA) plus ester) solventsen_US
dc.typeArticleen_US

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