Crystal Structure of 4-Bromo-3,4-Dichloro-1-(1-Morpholinyl)-1-(Decylsulfanyl)-2-Nitro-Buta-1,3-Diene
Küçük Resim Yok
Tarih
2010
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Springer/Plenum Publishers
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
The compound 4-bromo-3,4-dichloro-1-(1-morpholinyl)-1-(decylsulfanyl)-2-nitro-buta-3-diene was synthesized from the reaction of 4-bromo-1,3,4-trichloro-1(decylsulfanyl)-2-nitro-buta-1,3-diene with morpholine and characterized by elemental analysis, IR spectrum, UV spectra, H-1 NMR, C-13 NMR and X-ray single crystal determination. In the title compound, C18H29BrCl2N2O3S, crystallizes in the monoclinic space group P2(1)/c, a = 15.8326(4) angstrom, b = 8.9915(10) angstrom, c = 16.7528(5) angstrom, beta = 100.808(10)degrees, V = 2,342.6(3) angstrom(3), Z = 4, R-1 = 0.0590 and wR(2) = 0.0940. The morpholine ring adopts a chair conformation. The morpholine ring and the butadiene group are inclined at an angle of 113.4 (1)degrees. The butadiene unit is not planar as can be expected if the two double bonds are fully conjugated.
Açıklama
Anahtar Kelimeler
Butadiene unit, Crystal structure, Morpholine ring, Chair conformation
Kaynak
Journal Of Chemical Crystallography
WoS Q Değeri
Q4
Scopus Q Değeri
N/A
Cilt
40
Sayı
4
