Extractability of Fumaric Acid by Tributyl Amine (TBA) in Ketones and Alcohols
dc.contributor.author | Gemici, Aysegul | |
dc.contributor.author | Uslu, Hasan | |
dc.contributor.author | Kirbaslar, S. Ismail | |
dc.date.accessioned | 2024-03-13T10:35:11Z | |
dc.date.available | 2024-03-13T10:35:11Z | |
dc.date.issued | 2015 | |
dc.department | İstanbul Beykent Üniversitesi | en_US |
dc.description.abstract | Fumaric acid extraction from aqueous media by tributyl amine (TBA), which is an aliphatic amine, was studied at 298 K. Ketones (methyl isobutyl ketone (MIBK), heptan-2-one, octan-2-one) and alcohols (isoamyl alcohol, octan-1-ol, decan-1-ol) were selected as the diluent for dissolving TBA. Distribution ratio (K-D), loading ratio (T), and extraction degree (D-E) were calculated from experimental results. 96% efficiency was reached with isoamyl alcohol at 2.08 mol.kg(-1) of TBA concentration. Futher, the linear solvation energy relationship (LSER) modeling cooperated with Hidebrand-Hansen solubility parameters was used for prediction KD of alcoholic diluents. The LSER model gave closeness prediction to experimental data. | en_US |
dc.identifier.doi | 10.1021/acs.jced.5b00398 | |
dc.identifier.endpage | 2720 | en_US |
dc.identifier.issn | 0021-9568 | |
dc.identifier.issue | 9 | en_US |
dc.identifier.scopus | 2-s2.0-84941248191 | en_US |
dc.identifier.scopusquality | Q2 | en_US |
dc.identifier.startpage | 2717 | en_US |
dc.identifier.uri | https://doi.org/10.1021/acs.jced.5b00398 | |
dc.identifier.uri | https://hdl.handle.net/20.500.12662/4300 | |
dc.identifier.volume | 60 | en_US |
dc.identifier.wos | WOS:000361253500022 | en_US |
dc.identifier.wosquality | Q2 | en_US |
dc.indekslendigikaynak | Web of Science | en_US |
dc.indekslendigikaynak | Scopus | en_US |
dc.language.iso | en | en_US |
dc.publisher | Amer Chemical Soc | en_US |
dc.relation.ispartof | Journal Of Chemical And Engineering Data | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.title | Extractability of Fumaric Acid by Tributyl Amine (TBA) in Ketones and Alcohols | en_US |
dc.type | Article | en_US |