Reactive Extraction of (E)-Butenedioic Acid (Fumaric Acid) by Nontoxic Diluents

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dc.contributor.authorUslu, Hasan
dc.contributor.authorGemici, Aysegul
dc.contributor.authorGok, Asli
dc.contributor.authorKirbaslar, S. Ismail
dc.date.accessioned2024-03-13T10:35:15Z
dc.date.available2024-03-13T10:35:15Z
dc.date.issued2014
dc.departmentİstanbul Beykent Üniversitesien_US
dc.description.abstractIn this work, the equilibrium distribution of (E)-butenedioic acid (fumaric acid) between water and tridodecylamine (TDDA) or tributylamine (TBA) was carried out at 298 K. The organic phase was prepared using both TDDA and TBA in three nontoxic diluents (canola oil, sesame oil, and almond oil). The batch equilibrium experimental data are presented by calculation of the loading factor (Z), extraction efficiency (E), and distribution coefficient (K-D). The highest extraction efficiencies of 92.59 % and 92.50 % with values of KD equal to 12.50 and 12.40 were obtained with 0.789 mol center dot kg1 TDDA in canola oil and 2.080 mol.kg(1) TBA in canola oil. The extraction abilities of TDDA and TBA in different nontoxic natural diluents in terms of K-D and E were found to be in the order of canola oil > almond oil > sesame oil. Partition coefficients (P = 0.3819, 0.4739, and 0.7535) and dimerization constants (D = 83.64, 50.28, and 43.51) were calculated according to physical extraction for sesame oil, almond oil, and canola oil, respectively.en_US
dc.identifier.doi10.1021/je500634s
dc.identifier.endpage3772en_US
dc.identifier.issn0021-9568
dc.identifier.issn1520-5134
dc.identifier.issue11en_US
dc.identifier.scopus2-s2.0-84920434181en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage3767en_US
dc.identifier.urihttps://doi.org/10.1021/je500634s
dc.identifier.urihttps://hdl.handle.net/20.500.12662/4331
dc.identifier.volume59en_US
dc.identifier.wosWOS:000344977600053en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherAmer Chemical Socen_US
dc.relation.ispartofJournal Of Chemical And Engineering Dataen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.titleReactive Extraction of (E)-Butenedioic Acid (Fumaric Acid) by Nontoxic Diluentsen_US
dc.typeArticleen_US

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