Regioselective Substitution of Vinyl Halide by n-Alkyl Mercaptans and Subsequent Reactions with Versatile Cyclic Secondary Amines
Küçük Resim Yok
Tarih
2010
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Asian Journal Of Chemistry
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
Herein, we have described the preparation of several S-subtituted nitrobuta-1,3-dienes (3a-b) using the 4-bromo-1,1,3,4-tetrachloro-2-nitrobuta- 1,3-diene (1) with mercaptans (2a-b). Afterwards, N,S-substituted nitrobuta-1,3-diene compounds (5a, 7b and 9a-j) are obtained from the interaction of versatile secondary amines with the substituted product S-substituted nitrobuta-1,3-dienes (3a-b) in dichloromethane. Synthesized compounds have been characterized by using IR and NMR spectroscopy methods. Structural characterization is supported by elemental analysis and by mass spectrometry with accurate mass measurement of the molecular ion.
Açıklama
Anahtar Kelimeler
Nitro compounds, N,S-Substituted nitrodienes, Morpholine, Piperazine derivatives
Kaynak
Asian Journal Of Chemistry
WoS Q Değeri
Q4
Scopus Q Değeri
Q4
Cilt
22
Sayı
2
