Separation of Oxoethanoic Acid from Aqueous Solution by N-Methyl-N,N-dioctyloctan-1-ammonium Chloride

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dc.contributor.authorPehlivanoglu, Nil
dc.contributor.authorUslu, Hasan
dc.contributor.authorKirbaslar, S. Ismail
dc.date.accessioned2024-03-13T10:35:14Z
dc.date.available2024-03-13T10:35:14Z
dc.date.issued2014
dc.departmentİstanbul Beykent Üniversitesien_US
dc.description.abstractExtractability of oxoethanoic acid (glyoxylic acid (GA)) from aqueous solutions, with N-methyl-N,N-dioctyloctan-1-ammonium chloride (Aliquat 336 (A336)) in various diluents, including isoamyl alcohol, octan-1-ol, nonan-1-ol, decan-1-ol, methyl ethyl ketone (MEK), diisobuthyl ketone (DIBK), hexan-2-one, toluene, kerosene, and n-hexane has been investigated. Batch extraction results were calculated and reported as distribution coefficients (K-D), loading factors (Z), and extraction efficiency (E) at T = 298 K. These solvents with using A336 is more effective than a single solvent (K-D >> 1). Hexan-2-one has been found to be the most effective diluent with the highest value of K-D (17.37) at 1.31 mol.kg(-1) concentration of A336. The results of the liquid liquid equilibrium measurements were correlated by a linear solvation energy relationship (LSER) model which takes into account physical interactions and Freundlich and Langmuir equations. Experimental results of the oxoethanoic acid extraction are compared to model results.en_US
dc.identifier.doi10.1021/je500135e
dc.identifier.endpage941en_US
dc.identifier.issn0021-9568
dc.identifier.issue3en_US
dc.identifier.scopus2-s2.0-84896323859en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage936en_US
dc.identifier.urihttps://doi.org/10.1021/je500135e
dc.identifier.urihttps://hdl.handle.net/20.500.12662/4327
dc.identifier.volume59en_US
dc.identifier.wosWOS:000333005900051en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherAmer Chemical Socen_US
dc.relation.ispartofJournal Of Chemical And Engineering Dataen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.titleSeparation of Oxoethanoic Acid from Aqueous Solution by N-Methyl-N,N-dioctyloctan-1-ammonium Chlorideen_US
dc.typeArticleen_US

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