Effect of Diluents on the Extraction of Fumaric Acid by Tridodecyl Amine (TDA)
Küçük Resim Yok
Tarih
2015
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Amer Chemical Soc
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
Separation of fumaric acid from aqueous media with tridodecyl amine (TDA), which is a long chain aliphatic amine, was carried out at 298 K. Different categories of diluents, ketones (methyl iso butyl ketone (MIBK), 2-heptanone, and 2-octanone) and alcohols (isoamyl alcohol, 1-octanol) and 1-decanoL) were used to dissolve TDA. Distribution coefficients (K-D), extraction efficiency (E), and loading factors (Z) were obtained as a function a experimental results. The most operative diluent was determined as heptan-2-one with the highest distribution coefffdent (KD) value of 26.00. In additional to experimental studies, the linear solvation energy relationship (LSER) modeling with included Hidebrand Hansen solubility parameters was applied for alcoholic diluents. Predicted data by LSER gave good agreement with experimental data.
Açıklama
Anahtar Kelimeler
Kaynak
Journal Of Chemical And Engineering Data
WoS Q Değeri
Q2
Scopus Q Değeri
Q2
Cilt
60
Sayı
3
