Spectroscopic and structural aspects of the reactions of 1,4-quinones with sulfur and nitrogen nucleophiles

Basit Öğe Kaydı
dc.contributor.authorBayrak, Nilufer
dc.contributor.authorTuyun, Amac Fatih
dc.contributor.authorYildirim, Hatice
dc.contributor.authorOnul, Nihal
dc.date.accessioned2024-03-13T10:30:59Z
dc.date.available2024-03-13T10:30:59Z
dc.date.issued2014
dc.departmentİstanbul Beykent Üniversitesien_US
dc.description.abstractA series of 1,4-benzoquinone derivatives from 2,5-dichloro-3,6-diethoxy-1,4-benzoquinone and 2,6-dichloro-3,5-diethoxy-1,4-benzoquinone were prepared by nucleophilic substitution reactions of sulfur and nitrogen nucleophiles. Spectral techniques (H-1 NMR, C-13 NMR, FT-IR, and LC-MS) were employed to structurally characterize the reaction products of alkoxy, chloro substituted-1,4-benzoquinones with thiols and amines in the presence of sodium carbonate in ethanol at room temperature. The orientations and the regioselectivity of the reactions of alkoxy, chloro substituted-1,4-benzoquinones with various thiol and amine nucleophiles are discussed. (C) 2013 Academie des sciences. Published by Elsevier Masson SAS. All rights reserved.en_US
dc.identifier.doi10.1016/j.crci.2013.10.022
dc.identifier.endpage569en_US
dc.identifier.issn1631-0748
dc.identifier.issn1878-1543
dc.identifier.issue6en_US
dc.identifier.scopus2-s2.0-84901445631en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage563en_US
dc.identifier.urihttps://doi.org/10.1016/j.crci.2013.10.022
dc.identifier.urihttps://hdl.handle.net/20.500.12662/3639
dc.identifier.volume17en_US
dc.identifier.wosWOS:000337009500010en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevier France-Editions Scientifiques Medicales Elsevieren_US
dc.relation.ispartofComptes Rendus Chimieen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectSubstituted 1,4-quinonesen_US
dc.subjectThiolsen_US
dc.subjectAminesen_US
dc.subjectNucleophilesen_US
dc.subjectChloranilen_US
dc.titleSpectroscopic and structural aspects of the reactions of 1,4-quinones with sulfur and nitrogen nucleophilesen_US
dc.typeArticleen_US

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