Extractive Separation of Benzylformic Acid with Phosphoric Acid Tributyl Ester in CCI4, Decanol, Kerosene, Toluene, and Xylene at 298 K

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dc.contributor.authorAthankar, Kanti Kumar
dc.contributor.authorWasewar, Kailas L.
dc.contributor.authorVarma, Mahesh N.
dc.contributor.authorShende, Diwakar Z.
dc.contributor.authorUslu, Hasan
dc.date.accessioned2024-03-13T10:35:15Z
dc.date.available2024-03-13T10:35:15Z
dc.date.issued2015
dc.departmentİstanbul Beykent Üniversitesien_US
dc.description.abstractAn equilibrium isotherm of benzylformic acid with phosphoric acid tributyl ester in carbon tetrachloride, decanol, kerosene, toluene, and xylene at 298 K has been studied. The equilibrium data are discussed in terms of partition coefficient (P), dimerization constant (D), overall equilibrium complexation constant (E), and loading factor (phi). Moreover, the distribution coefficient (K-D) and extraction efficiency (eta%) with phosphoric acid tributyl ester in CCl4 is 0.199 to 52.1 and 16.6 to 98.1; in decanol, 5.66 to 45.9 and 85 to 97.9; in kerosene, 0.03 to 73.2 and 2.9 to 98.7; in toluene, 0.381 to 70.3 and 27.6 to 98.6; and in xylene, 0.322 to 57.7 and 24.3 to 98.3, respectively. The extraction efficiency of benzylformic acid was found to be more than 95 % with all these diluents. Loading factor phi < 0.5 was observed and it indicates that only 1:1 benzylformic acid-phosphoric acid tributyl ester complex in above said diluents were formed. Furthermore, the values of overall equilibrium complexation are determined with the relative basicity model using experimental result.en_US
dc.identifier.doi10.1021/je500943m
dc.identifier.endpage1022en_US
dc.identifier.issn0021-9568
dc.identifier.issue4en_US
dc.identifier.scopus2-s2.0-84927618298en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage1014en_US
dc.identifier.urihttps://doi.org/10.1021/je500943m
dc.identifier.urihttps://hdl.handle.net/20.500.12662/4334
dc.identifier.volume60en_US
dc.identifier.wosWOS:000353091500008en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherAmer Chemical Socen_US
dc.relation.ispartofJournal Of Chemical And Engineering Dataen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.titleExtractive Separation of Benzylformic Acid with Phosphoric Acid Tributyl Ester in CCI4, Decanol, Kerosene, Toluene, and Xylene at 298 Ken_US
dc.typeArticleen_US

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