Extractive Separation of Pentanedioic Acid by Amberlite LA-2 in Various Solvents

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dc.contributor.authorUslu, Hasan
dc.contributor.authorBamufleh, Hisham S.
dc.contributor.authorKeshav, Amit
dc.contributor.authorPal, Dharm
dc.contributor.authorDemir, Goksel
dc.date.accessioned2024-03-13T10:35:12Z
dc.date.available2024-03-13T10:35:12Z
dc.date.issued2016
dc.departmentİstanbul Beykent Üniversitesien_US
dc.description.abstractReactive extraction of pentanedioic acid using Amberlite LA-2 in different diluents, such as hexane, methylbenzene, kerosene, 4-methyl-2-pentanone, 2,6-dimethyl-4-heptanone, n-hexanone, 3-methyl-1-butanol, n-octanol, nnonanol, and n-decanol, respectively, was studied. At lower amine concentrations, K-D values of less than 1 were obtained but it improves as amine concentration was raised. Increase in amine concentration was found to increase the KD by 80-85% in inert diluents (hexane, methylbenzene and kerosene). In the chosen ketones, the extraction percentage follows the following trend 4-methyl-2-pentanone > DIBK > n-hexanone. Among the various diluents used, higher KD was obtained when alcohols were used as diluents. Mass action equilibria, linear solvation energy relationship modeling, and differential evolution (DE) was applied for estimating the model parameter and compare the model values with the experimental results of extraction equilibria.en_US
dc.identifier.doi10.1021/acs.jced.6b00141
dc.identifier.endpage2457en_US
dc.identifier.issn0021-9568
dc.identifier.issue7en_US
dc.identifier.scopus2-s2.0-84978768100en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage2450en_US
dc.identifier.urihttps://doi.org/10.1021/acs.jced.6b00141
dc.identifier.urihttps://hdl.handle.net/20.500.12662/4304
dc.identifier.volume61en_US
dc.identifier.wosWOS:000379988600030en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherAmer Chemical Socen_US
dc.relation.ispartofJournal Of Chemical And Engineering Dataen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.titleExtractive Separation of Pentanedioic Acid by Amberlite LA-2 in Various Solventsen_US
dc.typeArticleen_US

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