Extraction of aqueous of malic acid by trioctylamine extractant in various diluents
Küçük Resim Yok
Tarih
2010
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Elsevier
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
In this study malic acid were extracted from aqueous solution by different solvents with and without trioctylamine (TOA). The TOA was dissolved in five different esters (dimethyl phthalate, dimethyl adipate, dimethyl succinate, dimethyl glutarate. and diethyl carbonate), five different alcohols (isoamyl alcohol, hexan-1-ol, octan-1-ol, nonan-1-ol, and decan-1-ol) and two different ketones (diisobutyl ketone (DIBK) and methyl isobutyl ketone (MIBK)). The results are reported as distribution coefficients (K-D), loading factors (T-T), stoichiometric loading factor (T-S), separation factor (S-f) and extraction efficiency (E). The most effective solvent was determined as isoamyl alcohol with a distribution value coefficient of 17.811. The maximum values of equilibrium complexation constants in isoamyl alcohol for (acid:amine) (1:1) K-11 and (2:1) K-21 were 9.9 and 225.6, respectively. A linear solvation energy relationship (LSER) was accurately regressed to the experimental distribution coefficients. (C) 2009 Elsevier B.V. All rights reserved.
Açıklama
Anahtar Kelimeler
Reactive extraction, Malic acid, Trioctylamine (TOA), LSER model
Kaynak
Fluid Phase Equilibria
WoS Q Değeri
Q1
Scopus Q Değeri
Q2
Cilt
287
Sayı
2
