Comparison of the Antimony Cementation from Chloride Media Using Various Cementators

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dc.contributor.authorKucukoglu, Ozgun
dc.contributor.authorCetiner, Burcu Nilgun
dc.contributor.authorMorcali, Mehmet Hakan
dc.contributor.authorAktas, Serdar
dc.date.accessioned2024-03-13T10:30:54Z
dc.date.available2024-03-13T10:30:54Z
dc.date.issued2022
dc.departmentİstanbul Beykent Üniversitesien_US
dc.description.abstractThis study compares the cementation performance of metallic iron, metallic aluminum, and metallic tin in terms of the reaction conditions and parameters in synthetic antimony chloride solutions. The effects on the antimony recovery (%) caused by the cementators' types, stirring speed, reaction time, and temperatures were explored thoroughly. The cementation kinetics of antimony were also explored for each cementator. The activation energies were determined to be 10.99, 9.09, and 13.58 kJ mol(-1) for Al, Fe, and Sn, respectively. The results reveal that the reaction is diffusion controlled, and comparable results were obtained for each cementator. At 25 degrees C, 40 mg of iron powder was found to reduce all antimony ions (i.e., approx. 99% recovery), but even when 100 mg of Al and Sn cementators were used, the antimony recovery did not reach 100%. This result shows that iron is the best candidate to cement antimony out of the solution.en_US
dc.description.sponsorshipMarmara University Scientific Research Unit [FEN-C-DRP-090517-0283]en_US
dc.description.sponsorshipThis study is a part of the doctorate thesis of Mr. ozgun Kucukolu and was financially supported by the Marmara University Scientific Research Unit under the project FEN-C-DRP-090517-0283. The authors would like to thank American Manuscript Editors for editing the manuscript.en_US
dc.identifier.doi10.1007/s42461-021-00489-6
dc.identifier.endpage804en_US
dc.identifier.issn2524-3462
dc.identifier.issn2524-3470
dc.identifier.issue2en_US
dc.identifier.scopus2-s2.0-85123849709en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage793en_US
dc.identifier.urihttps://doi.org/10.1007/s42461-021-00489-6
dc.identifier.urihttps://hdl.handle.net/20.500.12662/3599
dc.identifier.volume39en_US
dc.identifier.wosWOS:000749009200001en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherSpringer Heidelbergen_US
dc.relation.ispartofMining Metallurgy & Explorationen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectCementationen_US
dc.subjectReductionen_US
dc.subjectReplacementen_US
dc.subjectAntimonyen_US
dc.subjectChloride mediaen_US
dc.titleComparison of the Antimony Cementation from Chloride Media Using Various Cementatorsen_US
dc.typeArticleen_US

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