Removal of highly toxic Cd(II) metal ions from aqueous medium using magnetic nanocomposite: adsorption kinetics, isotherm and thermodynamics

dc.contributor.authorAlqadami, Ayoub Abdullah
dc.contributor.authorNaushad, Mu
dc.contributor.authorAhamad, Tansir
dc.contributor.authorAlgamdi, Mohammad
dc.contributor.authorAlshahrani, Ahmed
dc.contributor.authorUslu, Hasan
dc.contributor.authorShukla, Sudheesh K.
dc.date.accessioned2024-03-13T10:33:22Z
dc.date.available2024-03-13T10:33:22Z
dc.date.issued2020
dc.departmentİstanbul Beykent Üniversitesien_US
dc.description.abstractIn this research, trisodium citrate (TSC) based magnetite (Fe3O4) nanocomposite was developed (Fe3O4@TSC) and applied as an efficient adsorbent for removal of Cd(II) from aqueous medium. The influence of experimental factors such as pH of the solution, amount of Fe3O4@TSC, temperature, contact time and initial Cd(II) concentration were studied. The results exhibited that the optimum pH value, equilibrium time and temperature were 7.6, 60 min and 298 K, respectively. The adsorption isotherm and kinetics were followed to the Langmuir isotherm and pseudo-second-order model, respectively. The maximum monolayer adsorption capacity was 312.5 mg/g at 298 K. The adsorption of Cd(II) on Fe3O4@TSC was exothermic in nature and spontaneous process based on negative values of Delta H degrees and Delta G degrees. The type of interactions between electropositive Cd(II) and the carboxylic group was electrostatic interactions.en_US
dc.description.sponsorshipDeanship of Scientific Research at King Saud University [RG-1436-034]; China/Shandong University International Postdoctoral exchange programen_US
dc.description.sponsorshipThe authors extend their appreciation to the Deanship of Scientific Research at King Saud University for funding this work through Research Group No. RG-1436-034. S.K. Shukla is thankful to the China/Shandong University International Postdoctoral exchange program.en_US
dc.identifier.doi10.5004/dwt.2020.25108
dc.identifier.endpage361en_US
dc.identifier.issn1944-3994
dc.identifier.issn1944-3986
dc.identifier.scopus2-s2.0-85086773811en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage355en_US
dc.identifier.urihttps://doi.org/10.5004/dwt.2020.25108
dc.identifier.urihttps://hdl.handle.net/20.500.12662/3926
dc.identifier.volume181en_US
dc.identifier.wosWOS:000545007400032en_US
dc.identifier.wosqualityQ4en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherDesalination Publen_US
dc.relation.ispartofDesalination And Water Treatmenten_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectMagneticen_US
dc.subjectNanocompositeen_US
dc.subjectIsothermen_US
dc.subjectKineticsen_US
dc.subjectToxic Cd(II)en_US
dc.titleRemoval of highly toxic Cd(II) metal ions from aqueous medium using magnetic nanocomposite: adsorption kinetics, isotherm and thermodynamicsen_US
dc.typeArticleen_US

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