Preparation of magnetic MIL-101 (Cr) for efficient removal of ciprofloxacin

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dc.contributor.authorBayazit, Sahika Sena
dc.contributor.authorDanalioglu, Selen Tugba
dc.contributor.authorSalam, Mohamed Abdel
dc.contributor.authorKuyumcu, Ozge Kerkez
dc.date.accessioned2024-03-13T10:30:51Z
dc.date.available2024-03-13T10:30:51Z
dc.date.issued2017
dc.departmentİstanbul Beykent Üniversitesien_US
dc.description.abstractMetal organic frameworks are widely used as adsorbent materials in recent years. In this study, the most prepared metal organic framework MIL-101 was prepared by hydrothermal method and featured magnetic property using co-precipitation method Fe3O4. Then, the prepared composite (MIL-101/Fe3O4) was first characterized using XRD, FTIR, SEM-EDS, and surface area analysis, then was used for the adsorptive removal of the most used antibiotic, ciprofloxacin (CIP). The effect of different adsorption variables which may affect the removal of CIP by MIL-101/Fe3O4 was investigated, as well as their adsorbent quantity, initial CIP concentration, pH, temperature, and contact time. The non-linear Langmuir and Freundlich isotherm were applied to experimental data. It was observed that rising solution temperature decreases adsorption efficiency, as the maximum adsorption uptake value was 63.28 mg g(-1) at 298 K and 22.93 mg g(-1) at 313 K, indicating the exothermic nature of the adsorption. The adsorption was studied kinetically and found to follow the pseudo-second-order kinetic model. The desorption of CIP from the MIL-101/Fe3O4 was investigated using three different eluents, and the results showed that phosphate-buffered solution was the most effective desorption eluent.en_US
dc.description.sponsorshipScientific and Technological Research Council of Turkey (TUBITAK) [213M376]en_US
dc.description.sponsorshipThis study was supported by the Scientific and Technological Research Council of Turkey (TUBITAK, Project no. 213M376).en_US
dc.identifier.doi10.1007/s11356-017-0121-0
dc.identifier.endpage25461en_US
dc.identifier.issn0944-1344
dc.identifier.issn1614-7499
dc.identifier.issue32en_US
dc.identifier.pmid28936584en_US
dc.identifier.scopus2-s2.0-85029684688en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage25452en_US
dc.identifier.urihttps://doi.org/10.1007/s11356-017-0121-0
dc.identifier.urihttps://hdl.handle.net/20.500.12662/3550
dc.identifier.volume24en_US
dc.identifier.wosWOS:000414958700057en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakPubMeden_US
dc.language.isoenen_US
dc.publisherSpringer Heidelbergen_US
dc.relation.ispartofEnvironmental Science And Pollution Researchen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectMIL-101en_US
dc.subjectMagnetic materialsen_US
dc.subjectCiprofloxacinen_US
dc.subjectAdsorptionen_US
dc.titlePreparation of magnetic MIL-101 (Cr) for efficient removal of ciprofloxacinen_US
dc.typeArticleen_US

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