Direct synthesis of tetrazine functionalities on polymer backbones

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dc.contributor.authorKara, Sinem Sipahioglu
dc.contributor.authorAtes, Mustafa Yasin
dc.contributor.authorDeveci, Gozde
dc.contributor.authorCetinkaya, Ahmet
dc.contributor.authorKahveci, Muhammet U.
dc.date.accessioned2024-03-13T10:30:39Z
dc.date.available2024-03-13T10:30:39Z
dc.date.issued2019
dc.departmentİstanbul Beykent Üniversitesien_US
dc.description.abstractTetrazine mediated inverse Electron Demand Diels-Alder Reaction (IEDDA) is an important modification technique due to its high selectivity and super-fast kinetics. Incorporation of tetrazine moieties on polymer chains requires multistep synthetic pathways and a post-polymerization step leading to functional polymeric materials. Such approaches involve separate syntheses of polymer and the molecule which will be employed in modification. Herein, we introduce a straightforward synthetic approach for direct synthesis of tetrazine groups on polymers as side chains. As model systems, tetrazine functional poly(N-isopropylacrylamide)-and poly(ethylene glycol)-based polymers from corresponding precursor polymers with nitrile moieties as pendant groups are prepared and IEDDA Click Reaction is achieved with trans-cyclooctene derivatives. The click reaction is monitored by both NMR and UV-vis spectroscopies. (c) 2018 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2019, 57, 673-680en_US
dc.description.sponsorshipTurkiye Bilimsel ve Teknolojik Aratirma Kurumu; Scientific and Technological Research Council of Turkey (TUBITAK) [214M175]en_US
dc.description.sponsorshipThis work has been financially supported by Turkiye Bilimsel ve Teknolojik Aratirma Kurumu and The Scientific and Technological Research Council of Turkey (TUBITAK, Project # 214M175).en_US
dc.identifier.doi10.1002/pola.29308
dc.identifier.endpage680en_US
dc.identifier.issn0887-624X
dc.identifier.issn1099-0518
dc.identifier.issue6en_US
dc.identifier.scopus2-s2.0-85058941183en_US
dc.identifier.scopusqualityN/Aen_US
dc.identifier.startpage673en_US
dc.identifier.urihttps://doi.org/10.1002/pola.29308
dc.identifier.urihttps://hdl.handle.net/20.500.12662/3463
dc.identifier.volume57en_US
dc.identifier.wosWOS:000458269900002en_US
dc.identifier.wosqualityN/Aen_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherWileyen_US
dc.relation.ispartofJournal Of Polymer Science Part A-Polymer Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectATRPen_US
dc.subjectDiels-Alder clicken_US
dc.subjectfunctionalization of polymersen_US
dc.subjectIEDDAen_US
dc.subjectmodificationen_US
dc.subjectpost-polymerizationen_US
dc.subjecttetrazineen_US
dc.titleDirect synthesis of tetrazine functionalities on polymer backbonesen_US
dc.typeArticleen_US

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