SYNTHETIC EXPLOITATION OF HALOGENATED ALKENES CONTAINING ELECTRON-WITHDRAWING GROUP (EWG): ACCESS TO VALUABLE 2,4-DINITROTHIOPHENES VIA RING-CLOSING AND RING-OPENING/RING-CLOSING PROTOCOLS

Tuyun, Amac Fatih2024-03-132024-03-1320130385-54141881-0942https://doi.org/10.3987/COM-13-12860https://hdl.handle.net/20.500.12662/3869With the goal of their exploitation for the synthesis of highly functionalized 2,4-dinitrothiophenes, 2-(2,3-dichloro-1,3-dinitroallylidene)-1,3-dithiolane (2), derived from the initial ring-closing of polyhalogenated nitrobutadienic building blocks with 1,2-ethanedithiol, were reacted with secondary amines. After protic work up, highly functionalized 2,4-dinitrothiophenes have been accomplished via ring-opening/ring-closing protocols.eninfo:eu-repo/semantics/closedAccessThiopheneNitrothiopheneDithiolaneButa-1,3-dieneNitrobutadienyl BlockSYNTHETIC EXPLOITATION OF HALOGENATED ALKENES CONTAINING ELECTRON-WITHDRAWING GROUP (EWG): ACCESS TO VALUABLE 2,4-DINITROTHIOPHENES VIA RING-CLOSING AND RING-OPENING/RING-CLOSING PROTOCOLSArticle10.3987/COM-13-128602-s2.0-84889249005259812Q4258987WOS:000330487600009Q3