Marti, Mustafa EsenZeidan, HaniUslu, Hasan2024-03-132024-03-1320160378-38121879-0224https://doi.org/10.1016/j.fluid.2016.02.039https://hdl.handle.net/20.500.12662/4162The present study is on the reactive extraction of pimelic acid (heptanedioic acid) from dilute aqueous solutions by trioctylamine (TOA) in decan-1-ol. The equilibrium studies were performed at 298 K and the results were used to calculate the values of distribution coefficient (K-D), loading factor (Z) and degree of extraction (E%). The maximum K-D was obtained as 6234 when initial concentrations of pimelic acid and TOA were 0.038 and 0.2 mol(-1) kg(-1), respectively. The extraction efficiency was 98.27% under these conditions. Moreover, Z values between 0.184 and 2.934 were obtained in the ranges of parameters studied. The data presents the formation of 1:1 and 1:2 pimelic acid-TOA solvates in the organic phase. A solvatochromic model (LSER) was applied to the equilibrium data and the K-D values obtained using the model show a good fit to the experimental outcomes. (C) 2016 Elsevier B.V. All rights reserved.eninfo:eu-repo/semantics/closedAccessReactive extractionPimelic acidTrioctylamineDecan-1-olDicarboxylic acidsArticle10.1016/j.fluid.2016.02.0392-s2.0-84960906125202Q2197417WOS:000374363000023Q2